How to unsync pictures from my iphone using itunes?

Seems like all i can do is overwrite the one folder for my pictures. How do I remove them totally?

I know that on your phone you can go to settings and then photoshare and turn this option off and then your pictures will not be lifted up into that cloud. I have never tried to stop it thru iTunes… But if you are talking about sharing the pictures from another computer too then you would have to turn the sharing option of photos off.

You would click on your iphone in iTunes and then it will show like the storage available etc… It is here where you can pick and choose what you would like to be sync to your iphone and you will go to the photos tab and click the box that says do not sync and this should take care of your problem.

Upload Pictures to a PC
1. Attach the sync cable to the USB port of your computer. Insert the other end into the bottom of your iPhone. Allow your iPhone and computer to establish a connection. Do NOT unplug the iPhone until instructed to do so.
2. Allow iTunes to open and begin syncing with the iPhone. Information will begin to be shared between your phone and the iTunes program on your Personal Computer
3. Wait for your PC to recognize the iPhone as a storage device. Follow the on-screen directions for transferring photos from your iPhone to a folder on your computer. Refer to the tips and reference section for information on programs that may be used.
4. Disconnect the iPhone from the snyc cable only when directed to do so. Wait until the syncing operation has completed to unplug your iPhone to avoid losing or damaging data. Upload Pictures to a Mac
5. Attach the sync cable to a USB port on your Mac and to the bottom of your iPhone. Do NOT unplug the iPhone until instructed to do so. Allow iTunes to open on your Mac and sync with your phone.
6.In iTunes, select the Photos tab at the top of the screen. Check the "Sync photos from" check-box and navigate to a folder on your Mac where you'd like to keep photos in sync. You can also choose "All folders" or "Selected folders."In iPhoto, click "Devices" in the list at the left, which will display photos on your device. Click "Import all" at the bottom right to copy all the photos from the device to the Mac, or hold down the Command key, click the individual photos you'd like to import, then click the "Import selected" button at the lower right.
7. Disconnect the sync cable from the iPhone only when iTunes indicates that the sync process has been completed.