My iphone 4s is not playing a song that I bought on iTunes?

I bought a song on iTunes and it downloaded and showed up twice on my playlist. One played and the other skipped and went right to the next song. I went onto iTunes and deleted both songs from the Library and synced my phone. After it was done, I checked and the song was still there! It looks white with a music note. It lasts a second like that then goes right to the next song. What is happening and how can I fix it?

Extra details: I have a iPhone 4S but very recently downloaded the IOS6 update. I already tried resetting Network Settings and syncing it.

Any help would be greatly appreciated?

That is very odd. However, my answer is to call apple's customer service/support.

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