Apple remote app not working?

I have two Wi-Fi networks. On my iPhone 4S the apple remote will work on one Wi-Fi network but not the other? The networks use the same Internet

The remote app will only control the computer on the network it's hooked up to. It doesn't matter if they're both using the same Internet, the router the computer or Apple TV is connected to has to be the same for the remote app to work.

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