ITunes isn't detecting my iPhone 5s?

So I basically just bought this phone yesterday and I've downloaded a lot of the songs in my iTunes library through my iCloud. But it seems all the songs that I recently managed to add to my iTunes library from my previous phone(galaxy s3) hasn't been downloaded. Is there something I'm missing? Any help would be very much so appreciated!

My iphone keeps downloading Home Alone when I connect it to iTunes?

I find this so annoying, my iPhone keeps dowloading Home Alone whenever i connect it to itunes, i already deleted it off my phone, i have no idea how to delete it off of itunes and its racking my head. Is there any way i can delete all my purachases off of itunes and off of my phone so they never sync together again?

Eternity Warriors 3 Hack Guide or Tips?

How can I Eternity Warriors 3 Hack or Cheats on my iPhone game. Is this possible to do Eternity Warriors 3 Gems Hack on game. I don't have money to buy Eternity Warriors 3 Gems. So I'm looking a way to get Eternity Warriors 3 gems hack guide or cheats guide.

Unlocking IPhone 4S (orange)?

My friend has just bought an iPhone 4S from work, it was an ex-sales phone and is locked to Orange, does he have to pay any extra to use it on Orange if he gets a new SIM card from them?

Revolution (tv series) how does the woman have an iphone?

I just started watching Revolution and i'm on episode 3. So basically first they showed that 15 years ago there was a blackout due to which earth no longer has working cars/factories/bulbs and stuff. And then in episode 3 they showed a woman holding an iphone and she says she keeps it because its the only thing that has her kids picture in it. I don't think iphone existed 15 years ago. Why'd they show an iphone? Why don't the producers/writers have enough common sense to show some kind of a flip phone or some big 1990's cell phone? (or is this show based in the future?)

What is price for iPhone 4 or 3GS?

I plan to get another iPhone after I get my iPhone 5S as my second phone. I was gave advice by other people that I should consider buy iPhone 4 or 3GS for the my case. So, I think that would be a good idea. I just wonder how much it cost to get one of those two.

How to schedule do not disturb on weekdays only?

I know I can schedule do not disturb from an hour to another but this is for the whole week. Is there a way to schedule it on weekdays only? Example: Monday to Friday, from 8 to 2. (Note: my iphone is jailbroken and I can install a tweak to add this functionality).

I accidentally deleted photos on my iphone 5?

I haven't backed up recently so itunes backup is not an option.
i haven't use my iphone too much after the deletion since it might overwrite the files.
Is there a way? I've tried other third party programs but that didn't work
I don't use icloud and photostream. My iphone is not jailbroken