Wi-Fi on new iPhone 5 won't work?

I just got my iPhone 5 2days ago and I tried to connect it to my home Wi-Fi but it kept saying unable to connect? But I can connect it on my iPod touch?

Without any details it is impossible to say where the problem lies.

Is your network name listed in the Wi-Fi section of the Settings? If it is and you tap the arrowhead to its right does it list an IP address having been allocated to the phone?

Have you tried turning the router off and on again?

Does the router have security settings that prevent unknown devices being able to use it? If so you will need to add the phone's MAC address (shown as Wi-Fi address in the Settings) to the list of known devices on the router.

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