Import duty/vat on item bought from a UK company dispatching from US?

I bought an iPhone 5s from a VAT registered company in the UK and they charged me VAT but the iPhone is being dispatched from the US to my home address. Would I pay additional fees when it arrives in the UK through customs?

Added (1). Also would they charge import VAT even though I paid VAT when I bought the phone?

There could be duty and handling charge to pay. They will bill you before releasing parcel if it is stopped and assessed. Not all parcels do get charged but it is possible it will.

You will have to pay import duty and collection fee as well as VAT, and when it goes wrong you will wish you had not of bothered. (it will be marked as an import)

No
VAT is only payable once. As long as you have evidence that you paid VAT, you will be OK

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